Partitioning of cations between coexisting single-and multi-site phases: A reply with incidental corrections

Details Partitioning of cations between coexisting single-and multi-site phases: A reply with incidental corrections Partitioning of cations between coexisting single-and multi-site phases: A reply with incidental corrections

Dec 1970

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1970gecoa..34.1361g&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 34, Issue 12, pp.1361-1364

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Scientific paper

Although the use of chemical potentials in treating species on sites within a single phase is formally correct, the use of potential differences or of other kinds of potentials may prove operationally more useful in the long run. The one site-two site model of and (1969) provides a reasonable explanation for existing Mg-Fe 2+ distribution data for coexisting ortho-and Ca-clinopyroxenes and, in the face of abundant evidence for intracrystalline partitioning in orthopyroxene, is preferred over a one-site model. The relations derived by Grover and Orville are correct, although several can be simplified.

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