Partition functions and related quantities of astrophysically significant molecules

Details Partition functions and related quantities of astrophysically significant molecules Partition functions and related quantities of astrophysically significant molecules

Jul 1985

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1985a%26a...148...93r&link_type=abstract

Astronomy and Astrophysics (ISSN 0004-6361), vol. 148, no. 1, July 1985, p. 93-96. FINEP-supported research.

Astronomy and Astrophysics

Astrophysics

11

Equipartition Theorem, Molecular Clouds, Molecular Energy Levels, Specific Heat, Thermodynamic Properties, Diatomic Molecules, Entropy, Error Analysis, Free Energy, High Temperature, Internal Energy, Polyatomic Molecules

Scientific paper

Available recent molecular data are used to compute partition functions, internal energies, specific heats, entropies, and free-energies for 53 molecular species containing H, C, N, O, S, Si, Mg, and Fe in the range from 1000 to 5000K. Simple functions, which reduce to fourth degree polynomials for the specific heats, are fitted to the results with high accuracy. Tables displaying the fitting constants are provided and a comparison is made with latest data.

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