Oxygen isotope composition of mantle peridotite

Statistics – Applications

Scientific paper

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Chemical Composition, Diamonds, Earth Crust, Earth Mantle, Laser Applications, Oxygen Isotopes, Peridotite, Rocks, Fluorination, Olivine

Scientific paper

The oxygen isotopic composition of 76 samples of olivine in spinel-, garnet- and diamond-facies peridotites, and as syngenetic inclusions within diamond has been determined by laser fluorination (LF). Delta O-18V-SMOW values of olivine are almost invariant, averaging 5.18 +/- 0.28 per mil (2 S.D.) with an overall range of 4.8-5.5 per mil. Coexisting clinopyroxenes display positive delta O-18cpx-olivine fractionations averaging 0.4 per mil that are consistent with isotopic equilibrium at normal mantle temperatures. The bulk compositions of spinel-, garnet- and diamond-facies mantle are similar, with a calculated bulk mantle delta O-18 values of +5.5 per mil. Olivin inclusions in diamonds of Archaean age yield delta O-18 values that are indistinguishable from olivine in post-Archaean mantle and the LF data do not provide evidence for gross spatial or temporal delta O-18 variation in peridotitic mantle. There is no evidence that mantle hydration processes impart distinctive oxygen isotope characteristics, other than a subtle isotopic disequilibrium disturbing pyroxenes relative to olivine.

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