Oxygen chemistry of shocked interstellar clouds. II - Effects of nonthermal internal energy on chemical evolution

Astronomy and Astrophysics – Astrophysics

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Chemical Evolution, Energy Distribution, Interstellar Chemistry, Molecular Clouds, Oxygen, Shock Wave Interaction, Fine Structure, High Temperature Gases, Internal Energy, Reaction Kinetics

Scientific paper

The effects of nonthermal vibrational, rotational, and fine-structure distributions on the evolution of oxygen-bearing species in shocked interstellar clouds are investigated. Using a one-fluid treatment of the shock structure, we carry out a calculation of the rotational and vibrational populations of molecular hydrogen in the cooling gas. The rates specific to the vibrational, rotational, and fine-structure temperatures of the reactants are explicitly included for the principal oxygen-hydrogen reactions. Shocks of velocity 10 km s-1 propagating in clouds of initial densities 10, 103 , and 105 cm-3 with zero and moderate magnetic field strengths are considered in detail.

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