Astronomy and Astrophysics – Astrophysics
Scientific paper
Dec 1996
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1996a%26a...316..270m&link_type=abstract
Astronomy and Astrophysics, v.316, p.270-274
Astronomy and Astrophysics
Astrophysics
7
Molecular Data, Molecular Processes, Methods: Laborotory, Ism: Molecules
Scientific paper
Efficient organometallic reactions between transition metals and polycyclic aromatic hydrocarbons (PAHs) have been proposed (Chaudret et al. 1991, New J. Chem. 15, 791, Serra et al. 1992A&A...260..489S) to occur in the interstellar medium (ISM). The present paper reports experimental measurements of the cross section for interactions between iron cations and neutral PAHs in the gas phase and the dissociation rates of the resulting organometallic (OM) complexes. The numerical simulation of the stabilisation and the fragmentation processes is in good agreement with the experimental data. These results provide accurate tools for future modellings to address both the problems of the formation of OM complexes and of the PAH charge in the ISM.
Boissel Pierre
de Parseval P.
Klotz Alain
Marty Philippe
Serra Giampaolo
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