Optical transitions in excited lithium+rare gas collision molecules and related interatomic potentials

Details Optical transitions in excited lithium+rare gas collision molecules and related interatomic potentials Optical transitions in excited lithium+rare gas collision molecules and related interatomic potentials

Apr 1999

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1999aipc..467..532b&link_type=abstract

The 14th international conference on spectral line shapes. AIP Conference Proceedings, Volume 467, pp. 532-545 (1999).

Computer Science

Intermolecular And Atom-Molecule Potentials And Forces

Scientific paper

Experimental collision induced spectra of Li*He and Li*Ne associated with the transitions 2PΛ-->3(D,P)Λ* as well as 3SΣ-->2SΣ are analyzed by means of quantum mechanical simulations using ab initio as well as semiempirical potentials and transition moment functions as input. By comparison, the observed spectral features can be understood in terms of the contributions from free-free and bound-free electronic transitions between the different molecular states, and the accuracy of the input data is tested.

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