Statistics – Computation
Scientific paper
Jun 2010
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..conferg14w&link_type=abstract
"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec
Statistics
Computation
Mini-Symposium: Metal Containing Molecules
Scientific paper
Copper hydroxide, CuOH, is one of the most thoroughly studied transition metal containing polyatomic molecules with the most recent investigation being the dispersed fluorescence and radiative lifetime study. The pure rotational spectrum was recorded and analyzed by Saito^'s group some time ago. Recently a high level {ab initio} calculation predicted ground state permanent electric dipole moments, μel, ranging in value from 5.52D to 3.98D depending upon methodology used to treat electron correlation. Here we report on the first molecular beam study of the B1A^"-X1A' band. The spectrum was recorded field-free and in the presence of a static electric field of up to 4000 V/cm. The hyperfine splitting is observed and analyzed for the first time. The determined μel values are used to evaluate the computational methodologies and are compared with those of other copper containing molecules.
C. N. Jarman, W. T. M. L Fernando, and P. F. Bernath J.Mol.Spectrosc.. 144 286, 1990.
C. Tao, C. Mukarakate, and S. A. Reid Chem.Phys.Lett.. 449 282, 2007.
C. J. Whitham, H. Ozeki, and S. Saito J.Chem.Phys. 112 641, 2000.
Steimle Timothy C.
Wang Fang
No associations
LandOfFree
Optical Stark Spectroscopy of the B1A^"-X1A' of CuOH does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Optical Stark Spectroscopy of the B1A^"-X1A' of CuOH, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Optical Stark Spectroscopy of the B1A^"-X1A' of CuOH will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-1592322