On the suppression of self discharge of the zinc electrodes of zinc-air cells and other related battery systems

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Alkaline Batteries, Cell Anodes, Charge Efficiency, Mercury Amalgams, Zinc-Oxygen Batteries, Alloying, Electric Discharges, Electrochemistry, Gas Evolution, Hydrogen

Scientific paper

A simple procedure is developed to determine the mercury content, without resorting to any analytical procedures, in the chemically amalgamated zinc electrode of zinc-air cells and other related battery systems. A small percentage of mercury is employed in these electrodes in order to increase the hydrogen overvoltage, minimize the self-discharge, and provide an equipotential surface ensuring uniform corrosion. A simple alloying method is developed as an alternative to the method of Bernard (1970). The ampere hour outputs of several experimental 1.4 V, 50 A h zinc-air alkaline cells are presented in order to show that this alloying procedure is more effective than the chemical method, especially when the amalgamated zinc is stored prior to use.

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