On the occurrence of apparent non-Henry's Law behaviour in experimental partitioning studies

Details On the occurrence of apparent non-Henry's Law behaviour in experimental partitioning studies On the occurrence of apparent non-Henry's Law behaviour in experimental partitioning studies

Jan 1993

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1993gecoa..57...47b&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 57, Issue 1, pp.47-55

Computer Science

7

Scientific paper

The strongest evidence for the occurrence of non-Henry's Law behaviour in magmatic systems is the apparent dependence of the garnet-melt partition coefficients for the REEs on REE concentration. Several of the garnet-melt pairs which showed deviations from Henry's Law when analysed using the optical autoradiography technique were reanalysed using secondary ion mass spectrometry. The SIMS results for these experiments showed that the partition coefficient is independent of concentration. It is concluded that the optical autoradiography technique can produce a spurious doubling of REE partition coefficients at low concentrations. Similar doubling of REE partition coefficients at low concentration have been observed with the optical autoradiography technique in plagioclase-melt systems. These deviations may also be an artefact of the autoradiographic technique. Non-Henry's Law behaviour has also been reported for Ni partitioning in olivine-melt systems. The data which deviate from Henry's Law are shown to be anomalous when compared with the data from all non-autoradiographic techniques, and from studies of phenocryst-matrix pairs. It is shown that for these experiments the partition coefficient is not dependent on the NiO concentration in either phase. It is concluded that these apparent deviations from Henry's Law are due to problems associated with the experimental procedure used and that the experiments do not record equilibrium partitioning. There are therefore good reasons for doubting the analyses of the autoradiographic studies which have found deviations from Henry's Law at low concentration. In the absence of non-autoradiographic data to the contrary, it is concluded that Henry's Law may be satisfied over a wide range of concentrations. There are therefore no data to suggest that partition coefficients measured in percent-level doping experiments cannot be used to model magmatic processes where the components of interest may only be present at trace concentrations.

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