On the Correct Analysis of the Maxwell Distribution

Mathematics – Logic

Scientific paper

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Scientific paper

The critical analysis of the Maxwell distribution is proposed. The main results of the analysis are as follows. (1) As is known, an experimental device for studying the Maxwell distribution consists of the following basic physical subsystems: (a) ideal molecular gas enclosed in a vessel (gas is in the equilibrium state); (b) molecule beam which is emitted from the small aperture of the vessel (the small aperture is a stochastic source of quantum particles). (2) The energy of the molecule of the beam does not represent random quantity, since molecules does not collide with each other. In this case, only the set of the monoenergetic molecules emitted by the stochastic source is a random quantity. This set is called a quantum gas. The probability pk that the quantum gas has the energy Enk is given by the Gibbs quantum canonical distribution: pk=p0,,-Enk / Enk T) . - T), k=0,;1,; where k is the number of molecules with energy En; T is temperature of the molecule in the vessel. (3) The average number of the molecules with energyEn represents the Planck distribution function: f=∑k=0^∞kpk ≡f(Planck). (4) In classical case, the expression Enf(Planck) represents the Maxwell distribution function: f(Maxwell)˜En,(Planck)˜v^2,;(-mv^2 / mv^2 2T) . - 2T). Consequently, the generally accepted statement that the Maxwell distribution function describes gas enclosed in a vessel is a logical error.

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