Occurrence of novel tetracyclic geochemical markers: 8,14-seco-hopanes in a Nigerian crude oil

Computer Science

Scientific paper

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Scientific paper

The occurrence of a novel class of tetracyclic triterpanes in petroleum is reported. These compounds presumably derive from pentacyclic hopanes by ring C opening. The identification of one C 30 H 54 8,14-seco-hopane has been effected by means of comparison with a mixture of synthetic isomeric compounds. Homologous seco-hopanes parallel the distribution of hopanes between C 27 and C 30 .

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