Observation of predissociated levels of CH/+/

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Astrophysics, Dissociation, Hydrocarbons, Interstellar Gas, Line Spectra, Positive Ions, Carbon, Laser Applications, Molecular Excitation

Scientific paper

The predissociation of CH(+) has been studied by observation of the appearance of C(+) photofragments as a function of excitation wavelength, near 3500 A. The dissociation energy of the C(+) fragments was also measured. Thirty-seven discrete transitions were observed to lead to dissociation within 350 kaysers of the dissociation limit. The most reasonable attribution of these observations is to the predissociation of the A 1Pi and a 3Pi states. If this is correct, then the number of quasi-bound levels which could contribute to the radiative association C(+)(2P) + H(2S) is much larger than previously expected

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