Nuclear Spin Dependence of Hydrogenic Plasmas in the Laboratory and the Diffuse Interstellar Medium

Details Nuclear Spin Dependence of Hydrogenic Plasmas in the Laboratory and the Diffuse Interstellar Medium Nuclear Spin Dependence of Hydrogenic Plasmas in the Laboratory and the Diffuse Interstellar Medium

Oct 2011

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mwac.meet..p08c&link_type=abstract

Midwest Astrochemistry Meeting 2011, held 21-22 October at the University of Illinois at Urbana-Champaign. http://midwest.astroc

Astronomy and Astrophysics

Astronomy

Scientific paper

Observations of diffuse molecular clouds have shown that the excitation temperature T(H3+) derived from the (J,K) = (1,0) (ortho) and (1,1) (para) rotational levels of H3+ does not necessarily agree with the kinetic temperature (T01) inferred from UV measurements of H2. In four of the five diffuse molecular cloud sight lines for which both H3+ and H2 observations are available, T(H3+) is lower than T01 by 30 K. The reaction H3+ + H2 → H2 + H3+ is expected to thermalize the H3+ nuclear spin distribution, but the interplay of nuclear spin selection rules and energetic restrictions at the low temperatures of the diffuse interstellar medium may prevent full thermalization at steady state. Alternatively, the nonthermal distribution could arise if H3+ does not experience a sufficient number of thermalizing collisions with H2 during its lifetime.
We have studied the nuclear spin dependence of the reaction of H3+ with H2 in the laboratory by measuring the ortho:para ratio of H3+ formed in plasmas of varying ortho:para H2 ratios. This study was performed in a hollow cathode cell which enabled the first measurements of this reaction at low temperature (130 K). From these measurements, we derived the ratio of the "proton hop" and "hydrogen exchange" rate coefficients as a function of temperature. The ratio, α, was found to decrease with temperature, already reaching the statistical limit of 0.5 at a temperature of 130 K.
Knowledge of α enables modeling of the ortho:para ratio of H3+ in diffuse molecular clouds. We have modeled the nuclear spin dependence of the formation, thermalization, and destruction processes of H3+, and found that the nonthermal distribution is not caused by nuclear spin selection rules or energetic restrictions in the H3+ + H2 reaction. Rather, it is likely caused by incomplete thermalization prior to H3+ destruction via electron dissociative recombination.

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