Nonequilibrium chemical effects in shocked interstellar clouds

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Chemical Effects, Interstellar Matter, Nonequilibrium Conditions, Reaction Kinetics, Shock Wave Interaction, Endothermic Reactions, Exothermic Reactions, Ionic Reactions, Molecular Interactions, Nonequilibrium Thermodynamics, Thermalization (Energy Absorption)

Scientific paper

The phase space method is utilized to calculate rate and "equilibrium" coefficients for the important reactive systems C+(H2)=CH+(H), O(H2)=OH(H), and OH(H2)=H2O(H) under the nonequilibrium conditions present in diffuse interstellar clouds subjected to shock waves. Substantial (order of magnitude) deviations from equilibrium thermal results are found only for the OH(H2)=H2O(H) reaction.

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