Non-proportional, non-linear results from X-ray emission techniques involving moderate-dilution rock fusion

Details Non-proportional, non-linear results from X-ray emission techniques involving moderate-dilution rock fusion Non-proportional, non-linear results from X-ray emission techniques involving moderate-dilution rock fusion

Aug 1966

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1966gecoa..30..745c&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 30, Issue 8, pp.745-756

Computer Science

Scientific paper

Five "standards", made by mixing standard rock samples G-1 and W-1 in various proportions, were fused with lithium tetraborate in a ratio of 35:65 and analysed for Si, Al, Fe, Ca, K, Ti and Mn by X-ray emission techniques. Elemental K -radiation intensities are not proportional to concentration, and calibration curves are thus non-linear over the ranges of composition represented. Computer-aided calculations confirm that large matrix effects exist for samples prepared by this fusion method and afford means for adjusting raw data.

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