New Univalent Cobalt Complexes of the [CoIdg2X2] Type

Details New Univalent Cobalt Complexes of the [CoIdg2X2] Type New Univalent Cobalt Complexes of the [CoIdg2X2] Type

Oct 1960

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1960natur.188..227m&link_type=abstract

Nature, Volume 188, Issue 4746, pp. 227 (1960).

Computer Science

1

Scientific paper

Dicyano - bis - dimethylglyoximato - cobaltate(III) complex, trans-K[CoIIIdg2(CN)2].3/2 H2O (a new compound)1 (dg = H3C.C(NOH).C(NO).CH3), was found to be reduced at the dropping mercury electrode in one step to a univalent cobalt complex polarographically in 1 M potassium chloride supporting electrolyte. The following electrode process was ascertained.

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