New spectroscopic studies of the Comet Tail (A2Πi X2Σ+) system of the CO+ molecule

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Scientific paper

In the electronic emission spectrum of the 12C16O+ molecule, 11 bands of the Comet Tail (A2Πi X2Σ+) system have been recorded and analyzed. Spin splitting in most of the observed lines of the 0 2, 1 0, 2 0, 2 1, 3 0, 4 0, 4 2, 6 0, 7 0, 7 1, and 8 1 bands, comprising nearly 3400 lines, has been recorded under high resolution by conventional spectroscopy. The rotational analysis of bands has been performed by nonlinear least-squares procedures and by means of effective Hamiltonians of Brown et al. and the rovibronic structure parameters have been obtained. The data of bands of the A X system and earlier analyzed bands of the B X and B A systems have been merged together. As a result of this global fit, the state of information about the energy structure has been significantly enlarged for the A state and enlarged and improved for the X state. Also RKR potential curves for both states and Franck Condon factors as well as r-centroids of the Comet Tail system of CO+ have been calculated.

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