New light on an old subject: An FT-Raman study of ion association in aqueous solutions of cobalt(II) nitrate

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Scientific paper

Raman spectroscopy has been ignored as a tool to investigate ion association in highly colored salt solutions. With the advent of FT-Raman many of the problems associated with conventional Raman spectroscopy have been eliminated or minimized. This study shows that it is possible to study ion association in highly colored aqueous cobalt(II) nitrate solutions. Cobalt (II) nitrate has been found to be highly associated in aqueous solution in the concentration range 0.5 m to near saturation. The ion species in solution consist of the free aquated nitrate and cobalt(II) ions and two aquated metal nitrate ion pairs.

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