New H and H_2 Reactions with Small Hydrocarbon Ions and Their Roles in Benzene Synthesis in Dense Interstellar Clouds

Astronomy and Astrophysics – Astronomy

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Subject Headings: Ism: Clouds, Molecular Processes

Scientific paper

This paper summarizes the most recent knowledge concerning normal and three-body association ion-molecule reactions between small hydrocarbon ions (C_mH^+_n m=1-6, n=0-9) and the neutral reactants H and H_2. Selected radiative association reaction rate coefficients have been calculated and estimated based on three-body laboratory results. Some of the normal and radiative association rate coefficients have been incorporated into our ``new standard'' model of dense cloud interstellar chemistry. We find that atomic H provides an insufficiently appreciated mechanism to increase the level of saturation of C_mH^+_n ions, with m>3 in dense interstellar clouds despite the fact that the H/H_2 abundance ratio is only 10^-4. New model results show in particular that a significant abundance of the basic aromatic cyclic molecule benzene (c-C_6H_6) can now be produced in dense clouds.

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