Natural sulphurization of ketones and aldehydes: A key reaction in the formation of organic sulphur compounds

Details Natural sulphurization of ketones and aldehydes: A key reaction in the formation of organic sulphur compounds Natural sulphurization of ketones and aldehydes: A key reaction in the formation of organic sulphur compounds

Dec 1993

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1993gecoa..57.5111s&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 57, Issue 23-24, pp.5111-5116

Computer Science

1

Scientific paper

Acids, ketones, aldehydes, and alcohols were tested in the laboratory as substrates for hydrosulphurization under mild conditions. Ketone and aldehyde model compounds (i.e., 2-nonanone, nonanal, cholestan-3-one and phytenal) formed significant amounts of organic sulphur compounds, in which the oxo group was substituted by a polysulphide moiety. These results are used to explain the formation of several organic sulphur compounds reported in immature S-rich sediments.

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