Natural source of tetraalkyllead in air

Mathematics – Logic

Scientific paper

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Scientific paper

THE biological methylation of inorganic mercury in sediments in both aerobic and anaerobic conditions is well known1, and attention has focussed on the possibility of a similar process for lead in the environment. It has been possible to methylate lead in laboratory studies, with the resultant evolution of gaseous tetramethyllead2-4, but there is still considerable doubt as to whether such processes occur in the environment5. A report6 that tetraalkyllead accounts for 10-24% of the total lead in the liver of fresh and frozen samples of cod and 39% of the total lead in mackerel muscle lends credence to the possibility. However, we can now present firm evidence of a natural source contributing tetraalkyllead to the atmosphere.

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