Modeling of collision-induced infrared absorption spectra of H2-H2 pairs in the fundamental band at temperatures from 20 to 300 K

Statistics – Computation

Scientific paper

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Absorption Spectra, Astronomical Models, Hydrogen, Infrared Absorption, Planetary Atmospheres, Quantum Mechanics, Ground State, Rotational Spectra, Vibrational Spectra

Scientific paper

The 20-300 K free-free rotovibrational collision-induced absorption (RV CIA) spectra of H2-H2 pairs are presently obtained by a numerical method which, in addition to closely matching known CIA spectra of H2-H2, can reproduce the results of the quantum-mechanical computations to within a few percent. Since the spectral lineshape parameters are derivable by these means from the lowest three quantum-mechanical spectral moments, these outer-planet atmosphere-pertinent model spectra may be computed on even small computers.

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