Millimeter-wave spectrum of the CCO radical

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Abundance, Carbon Suboxides, Microwave Spectra, Millimeter Waves, Molecular Spectra, Transition Probabilities, Carbon Monoxide, Hamiltonian Functions, Interstellar Matter, Least Squares Method, Radicals, Rotational Spectra

Scientific paper

The pure rotational spectrum of the CCO radical in the 3Σ- ground electronic state has been observed in the laboratory in the region 45 - 185 GHz. The radical was generated in a 3.5 m long free space absorption cell by a DC glow discharge in carbon suboxide (C3O2). Seven rotational transitions of N = 2<-1 to 8<-7 in each triplet sublevels were precisely measured and the observed frequencies were least-squares analyzed to obtain molecular constants.

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