Microwave spectrum of the IO radical

Computer Science

Scientific paper

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Scientific paper

The two lowest rotational transitions of the IO radical in the 2Π3/2 ground electronic state have been observed by means of a Stark modulated spectrometer. The effective rotational constants in the 2Π3/2 state, the centrifugal distortion constant, the axial component of the magnetic hyperfine interaction, and the nuclear electric quadrupole coupling constant are determined accurately. It was necessary to take into account the second-order effects from the matrix elements off-diagonal in J for the analysis of the hyperfine structure. An equilibrium internuclear distance re is calculated to be 1.8677 +/- 0.0028 Å from the effective rotational constant B0(2Π3/2), combined with α3 from the A2Π --> X2Π transition.

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