Microwave Spectrum of the Hydrogen Bonded Complex Between Propiolic and Formic Acid

Details Microwave Spectrum of the Hydrogen Bonded Complex Between Propiolic and Formic Acid Microwave Spectrum of the Hydrogen Bonded Complex Between Propiolic and Formic Acid

Jun 2010

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..confeth09d&link_type=abstract

"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec

Other

Microwave (Rotational)

Scientific paper

The microwave spectrum of the gas phase complex formed between propiolic acid (HCCCOOH) and formic acid (HCOOH) along with 5 other isotopomers were obtained using a pulsed beam fourier transform microwave spectrometer. The spectra of the HC12OOH and HC13OOH isotopomers were each fit to two sets of rotational constants. The parent rotational constants were 5988.7(8), 927.782(7), 803.720(7) and 5988(1), 927.779(9) 804.058(9) MHz respectively. Isotomers containing deuterium in the OH bonds, HCOOD and HCCCOOD, do not show this feature. We tentatively assign the two sets of rotational constants to the two different inversion states for the concerted proton tunnelling in the hydrogen bonds.

Affiliated with

Also associated with

No associations

Rating

Microwave Spectrum of the Hydrogen Bonded Complex Between Propiolic and Formic Acid does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Microwave Spectrum of the Hydrogen Bonded Complex Between Propiolic and Formic Acid, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Microwave Spectrum of the Hydrogen Bonded Complex Between Propiolic and Formic Acid will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-1593796