Other
Scientific paper
Jun 2010
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..confeth15k&link_type=abstract
"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec
Other
Microwave (Rotational)
Scientific paper
The trans-ethyl methyl ether molecule (CH_3CH_2OCH_3) has two methyl group internal rotors which are equivalent to the two vibrational motions, ν28 and ν29. There is another low-lying torsional motion which is a skeltal torsion (ν30) and does not cause splitting. The microwave spectra of the trans-ethyl methyl ether molecule in the ν28 = 1, ν29 = 1, and ν30 = 1 have been studied and interactions between these states were discussed. In this paper we report results on the ν30 = 2, and 3 state.
The analysis based on Hougen's tunneling matrix formulation considering two methyl groups are used.
We try to interpret tunneling parameters obtained in the present analysis quantitatively from the viewpoint of torsion-torsion interaction.
Kobayashi Kaori
Murata Keigo
Ohashi Nobukimi
Tsunekawa Shozo
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