Microwave Spectra and Structure of CF_3I\cdotsCO

Details Microwave Spectra and Structure of CF_3I\cdotsCO Microwave Spectra and Structure of CF_3I\cdotsCO

Jun 2011

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..confemh02s&link_type=abstract

"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec

Computer Science

Microwave

Scientific paper

A Chirped Pulse Fourier transform Microwave spectrometer has been used to measure the pure rotational spectrum of CF_3I\cdotsCO. This complex is generated by supersonic expansion of a gas sample containing a small percentage of CF_3I, and CO in argon. The rotational constant B0, centrifugal distortion constants, Δ_J and Δ_JK, and nuclear quadrupole coupling constant for iodine, χAa(I), have been determined for each of CF_3ICdots12C16O, CF_3ICdots13C16O and CF_3I\cdots 12C18O allowing determination of the distance between the two sub-units. The complex is a prolate symmetric top with C3v symmetry.

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