Mechanism of the Thermal Decomposition of Furan

Details Mechanism of the Thermal Decomposition of Furan Mechanism of the Thermal Decomposition of Furan

Jun 2009

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2009mss..confemj12v&link_type=abstract

"International Symposium On Molecular Spectroscopy, 64th Meeting, Held 22-26 June, 2009 at Ohio State University. http://molspec

Computer Science

Matrix/Condensed Phase

Scientific paper

Both furan (C_4H_4O) and furfural (C_4H_3O-CHO) areimportant products in biomass pyrolysis. We have used a resistively-heated SiC tubular reactor with a 30 microseconds residence time to study the thermal cracking of furan. The decomposition products are identified by two independent techniques: 118.2 nm VUV photoionization mass spectroscopy and infrared spectroscopy. We observe three different thermal dissociation channels leading to: a) CH_3CCH + CO b) HCCH + CH_2CO c) HCCCH_2.

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