Luna 20 pyroxenes: exsolution and phase transformation as indicators of petrologic history

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Scientific paper

Pyroxenes from our sample of Luna 20 soil are predominantly orthopyroxene with subordinate pigeonite. The orthopyroxenes are chromium-rich bronzites and contain submicroscopic lamellae of augite in a twinned orientation exsolved on (100). These lamellae have a composition close to the diopside-hedenbergite join. Asymmetric diffuse streaks parallel to a * indicate stacking faults parallel to (100) and possibly very thin (10-20 Å) lamellae of clinobronzite parallel to (100). Pigeonite crystals are very complex crystallographically and chemically, with optically visible (001) augite exsolution lamellae and two sets of chromite exsolution lamellae. In addition, there are submicroscopic (100) augite lamellae and a second generation of clinohypersthene lamellae which appear to have exsolved from the (001) augite lamellae. The clinohypersthene host, which has a large number of stacking faults parallel to (100), has partially inverted to hypersthene of the same composition. The hypersthene occurs as very fine lamellae (less than 1000 Å) parallel to the (100) plane of the clinohypersthene. X D Fe-Mg values for five host-lamellae pairs in pigeonite K-4 indicate a significant amount of subsolidus readjustment. We tentatively conclude that many of the bronzite and pigeonite crystals were derived from rocks crystallized from a high level magma chamber in the lunar highland crust.

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