Laser molecular spectroscopy - Determination of the parameters of the as R/1, 1/ vibrational-rotational line of the nu2 band of ammonia in an atmosphere with other gases

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Ammonia, Atmospheric Composition, Laser Outputs, Molecular Spectroscopy, Spectral Bands, Vibrational Spectra, Carbon Dioxide Lasers, Gas Mixtures, Molecular Oscillations, Molecular Rotation, Quadrupoles, Spectral Line Width

Scientific paper

The absorption of CO2-laser radiation by ammonia at the R(14) line of the 10.6-micron band in mixtures with N2, H2, Ne, Ar, Kr and Xe is studied. Coefficients of broadening and line shift were obtained for the as R(1, 1) line of the nu2 band of (N-14)H3. A modified Lorentz function was used to analyze the absorption-line shape and an analysis of measurement errors was performed. The temperature dependence of the broadening coefficient of ammonia in an atmosphere of NH3, N2 and H2 was determined.

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