Lambda-type doubling in SiH molecule

Details Lambda-type doubling in SiH molecule Lambda-type doubling in SiH molecule

Nov 1975

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1975natur.258..133w&link_type=abstract

Nature, vol. 258, Nov. 13, 1975, p. 133, 134.

Astronomy and Astrophysics

Astronomy

9

Fine Structure, Hydrides, Interstellar Gas, Molecular Spectra, Silicon Compounds, Molecular Energy Levels, Molecular Rotation, Radio Spectra, Vibrational Spectra, Wave Functions

Scientific paper

In the case of SiH, which is of interest as a probable interstellar species, the only available prediction for the radioastronomical frequency band must be made by extrapolating Lambda-doubling from high rotational levels populated in laboratory experiments to low rotational levels. Predictions made with the aid of the approximations introduced by Van Vleck (1929) are considered. Data obtained in the calculations are presented in a table.

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