Laboratory Rotational Spectrum of Nickel Monochloride in the Ground Electronic 2Π3/2 State

Astronomy and Astrophysics – Astronomy

Scientific paper

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Ism: Molecules, Molecular Data

Scientific paper

The pure rotational spectrum of nickel monochloride in the 2Π3/2 ground electronic state has been observed in the laboratory for the first time in the millimeter- and submillimeter-wave region. The NiCl radical was generated in a free-space absorption cell by a DC glow discharge in a mixture of Cl2 and Ar using a nickel cathode, from which nickel atoms were supplied by the sputtering reaction. The rotational, centrifugal distortion, and fine-structure constants were determined by a least-squares method using an effective Hamiltonian for a 2Π3/2 electronic state.

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