Laboratory millimeter-wave spectrum of iron monoxide, FeO

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Cosmochemistry, Iron Oxides, Microwave Spectra, Millimeter Waves, Molecular Spectroscopy, Electron Transitions, Molecular Rotation, Rotational Spectra

Scientific paper

Laboratory observations have been conducted at 154 and 184 GHz for FeO's pure rotational spectrum in the 5Delta-i ground electronic state, generating the radical in a 1-m long, free-space absorption cell by means of a DC glow discharge in a mixture of ferrocene and oxygen. Two rotational transistions of J = 5 - 4 and 6 - 5 in each of the three lowest spin sublevels with Omega values of 4, 3 and 2 were precisely measured, and the frequencies obtained were subjected to least-squares analysis using a Hamiltonian appropriate for the 5Delta-i electronic state.

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