Laboratory millimeter-wave spectrum of chromium monochloride

Details Laboratory millimeter-wave spectrum of chromium monochloride Laboratory millimeter-wave spectrum of chromium monochloride

May 1995

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1995apj...445l..67o&link_type=abstract

Astrophysical Journal, Part 2 - Letters (ISSN 0004-637X), vol. 445, no. 1, p. L67-L68

Astronomy and Astrophysics

Astrophysics

14

Chlorides, Chromium Compounds, Interstellar Matter, Millimeter Waves, Radicals, Rotational Spectra, Spectrum Analysis, Transition Metals, Aluminum Compounds, Energy Levels, Gas Mixtures, Glow Discharges, Hamiltonian Functions, Helium, Least Squares Method

Scientific paper

The pure rotational spectrum of chromium monochloride in the 6Sigma+ ground electronic state has been observed in the laboratory in the millimeter-wave region. The CrCl radical was generated in a free-space absorption cell by a DC glow discharge in a mixture of AlCl3 vapor and He using stainless steel electrodes. The chromium atom was supplied from the electrodes by the sputtering reaction. The rotational, centrifugal distortion, and several fine-structure constants were determined by the least-squares method using the Hamiltonian for a 6Sigma electronic state.

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