Laboratory measurements of photoabsorption cross sections of SO_2 between 190 and 220 nm.

Astronomy and Astrophysics – Astronomy

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Determination of the chemical composition of the atmosphere of Io from Hubble Space Telescope observations in the 190-220 nm wavelength region requires knowledge of the photoabsorption cross sections of SO_2 at temperatures ranging from 110 to 300 K. We have initiated a laboratory program to measure SO_2 absorption cross sections with very high resolving power (lambda /delta lambda =~ 500,000) and at temperatures appropriate to the Io atmosphere. Previous photoabsorption measurements, with lambda /delta lambda <= 100,000, have been unable to fully resolve the very congested SO_2 spectrum. Our measurements are being undertaken at Imperial College, London, using an ultraviolet Fourier transform spectrometer (Thorne et al. 1987. J. Phys. E 20, 54). We present new room temperature SO_2 photoabsorption cross sections in the 190-220 nm region measured with an instrumental resolution of 0.0004 nm. These high-resolution cross sections are compared to previous, lower-resolution, data. This work is supported by NASA Grant NAGW-5200.

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