Laboratory Measurement of the J=1-0 Transitions of Sodium Hydride and Potassium Hydride

Astronomy and Astrophysics – Astronomy

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Ism: Molecules, Molecular Data

Scientific paper

The J=1-0 transitions of 23NaH and 39KH were measured in the millimeter-wave region with a source modulation millimeter-wave spectrometer. The NaH and KH molecules were generated from sodium grains and a potassium ingot, respectively, in a DC glow discharge through hydrogen gas. The line splittings caused by the hyperfine structure due to the 23Na and 39K nuclei (I=3/2) were observed in the rotational transitions for the first time. The central transition frequency, the nuclear electric quadrupole coupling constant, and the nuclear magnetic spin-rotation coupling constant were determined for each species by line-shape simulation.

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