Laboratory Measurement of Rotational Spectrum of the 18OH Radical Using a Tunable Far-Infrared Spectrometer

Astronomy and Astrophysics – Astronomy

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Line: Identification, Methods: Laboratory, Molecular Data

Scientific paper

Far-infrared transitions between the lower rotational levels of the 18OH radical in the X2Π state have been observed in the laboratory with a high-precision far-infrared spectrometer using a tunable radiation source. From a least-squares analysis of the observed far-infrared data together with the microwave A-doubling data, molecular parameters of 18Π in X211 have been determined to a better precision than those obtained from laser magnetic resonance data and the microwave data (Comben et al. 1986). The hyperfine structure parameters for 18OH are determined for the first time.

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