Laboratory detection of the protonated carbon dioxide by submillimeter wave spectroscopy

Astronomy and Astrophysics – Astrophysics

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Astronomical Spectroscopy, Carbon Dioxide, Molecular Ions, Radio Spectroscopy, Submillimeter Waves, Environmental Laboratories, Interstellar Gas, Line Spectra, Proton Impact, Space Environment Simulation

Scientific paper

Six lines corresponding to the K = 0 and K = 2 components of the J = 15-16 and 16-17 transitions of HCO2(+) have been observed in the laboratory by discharging a mixture of H2 + CO2 + Ar. These lines have been fitted together with the astrophysical lines attributed to HCO2(+) or HOCN, and the B and C constants as well as centrifugal distorsion constants have been determined. This gives a definitive confirmation of the attribution of these astrophysical lines to the protonated carbon dioxide.

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