Laboratory detection of the C_8_H radical.

Astronomy and Astrophysics – Astrophysics

Scientific paper

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17

Line: Identification, Molecular Data, Techniques: Spectroscopic, Ism: Molecules, Radio Lines: Ism

Scientific paper

The C_8_H radical has been detected in an argon-acetylene discharge, conclusively confirming the identification by Cernicharo and Guelin in the accompanying Letter of their new linear molecule in IRC+10216. In addition to the ground ^2PI_3/2_ rotational ladder, the ^2PI_1/2_ ladder 19cm^-1^ above ground has been detected, and the entire fine structure-rotational spectrum calculated. The standard ^2PI Hamiltonian fits the laboratory measurements of more than 30 radio lines between 80 and 100GHz to high accuracy; yields precise values for the rotational, fine structure, and lambda-doubling constants; and allows the astronomically most interesting lines in the radio spectrum to be predicted to an uncertainty of 0.1km/s or better.

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