Laboratory detection of the C6H radical

Details Laboratory detection of the C6H radical Laboratory detection of the C6H radical

Jan 1988

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1988a%26a...189l..13p&link_type=abstract

Astronomy and Astrophysics (ISSN 0004-6361), vol. 189, no. 1-2, Jan. 1988, p. L13-L15.

Astronomy and Astrophysics

Astronomy

27

Atomic Interactions, Hydrocarbons, Molecular Chains, Molecular Rotation, Radicals, Radio Astronomy, Astronomical Spectroscopy, Line Spectra, Millimeter Waves, Radio Spectra

Scientific paper

The linear carbon chain radical C6H has been detected in the same acetylene and helium discharge in which C4H is observed. Thirty millimeter-wave rotational transitions were measured, 20 in the 2Pi(1/2) ladder between 146.5 and 199.6 GHz and 10 in the 2Pi(3/2) ladder between 167.7 and 198.2 GHz. Precise values for the rotational, fine structure, and lambda-doubling parameters were derived from a simultaneous fit to the 30 laboratory lines and 57 astronomical lines allowing calculation of the entire radio spectrum to the accuracy required by radio astronomy.

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