Ion-molecule reaction probabilities near 10 K

Mathematics – Probability

Scientific paper

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Gas-Ion Interactions, Interstellar Chemistry, Ionic Reactions, Molecular Clouds, Molecular Interactions, Ammonia, Hydrogen, Nitrogen, Probability Distribution Functions, Reaction Kinetics

Scientific paper

Reaction probabilities have been measured near 11K using an ion trap technique for some processes important for molecule formation in interstellar clouds. Probabilities were determined at 11K ≤ T ≤ 20K for the abstraction processes N++H2→NH++H and NH3++H2→NH4++H. New experimental upper limits were determined for the radiative association reactions C++H2→CH2++hν and HCO++H2→H3CO++hν. Reaction rate coefficients were deduced from the probabilities.

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