Intercomparison of ballloon-borne cryogenic whole air samplers during the MAP/GLOBUS 1983 campaign

Computer Science

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Air Sampling, Balloon-Borne Instruments, Cryogenic Equipment, Middle Atmosphere, Stratosphere, Chlorofluoromethane, Comparison, Gas Chromatography, Halocarbons

Scientific paper

Two cryogenic whole air samplers were flown almost simultaneously, but on separate gondolas as part of the MAP/GLOBUS campaign in September 1983. Two sets of air samples were collected between 34 and 10 km altitude. This paper describes the technical aspects of this intercomparison. The data obtained from gas-chromatographic analyses for CH4, N2O, CFCl2 and CF2Cl2 are discussed. An error analysis shows that the observational uncertainty of CH4, N2O and CF2Cl2 is comparable to the analytical error for these gases. In the case of CFCl3 it indicates the existence of unidentified experimental uncertainties.

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