Interaction of ozone and hydrogen peroxide in water - Implications for analysis of H2O2 in air

Details Interaction of ozone and hydrogen peroxide in water - Implications for analysis of H2O2 in air Interaction of ozone and hydrogen peroxide in water - Implications for analysis of H2O2 in air

Mar 1982

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1982georl...9..231z&link_type=abstract

Geophysical Research Letters, vol. 9, Mar. 1982, p. 231-234.

Computer Science

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23

Air Pollution, Atmospheric Chemistry, Hydrogen Peroxide, Molecular Interactions, Ozone, Aqueous Solutions, Atmospheric Sounding, Chemical Equilibrium, Hydrolysis, Reaction Kinetics, Water

Scientific paper

It is demonstrated experimentally that since ozone and/or its decomposition products can both produce and destroy H2O2 in aqueous solution, techniques employing aqueous traps for the measurement of H2O2 in air are subject to large interferences from O3-H2O2 reactions. It is shown that H2O2 levels in the traps reach a plateau with continuous bubbling, indicating that a state of dynamic equilibrium involving H2O2 destruction was established. The ozone decomposition products implicated in the process are OH and O3(-).

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