Intensity Measurements on the C2 (d3Pi g-a3Pi u) Swan band System. I. Intercept and Partial Band Methods

Astronomy and Astrophysics – Astrophysics

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The rotational line intensity, partial band intensity and peak band intensity methods (the latter used in conjunction with computer-generated synthetic spectra) have been used to interpret photoelectric and photographic measurements on the astrophysically important C2 Swan band system, stably excited in a direct current discharge through C2Cl6 + A. All measurements lead to a consistent (within 5%) expression for the variation of the electronic transition moment with internuclear separation of Re(r) = C(1.00-0.52r) 1.120 < r < 1.488A. Critical assessment of recently published oscillator strength measurements on the (0,0) band suggest that C is 13.02 × 10-18 cm e.s.u. (± 25%). A table of absolute band strengths, oscillator strengths and Einstein A coefficients has thus been calculated.

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