Computer Science
Scientific paper
Jun 2010
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..confetf02r&link_type=abstract
"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec
Computer Science
Mini-Symposium: Metal Containing Molecules
Scientific paper
Metal ligand and metal oxide ligand complexes are generated in a laser vaporization/supersonic expansion cluster source and are mass selected and studied using infrared spectroscopy in the 600-4000 wn region using a tunable infrared OPO. Several different systems are investigated and some show evidence for intracluster reactions to form metal oxide species or coupling of coordinating ligands. In particular the V(CO2)n+ system shows evidence for the onset of in intracluster reaction at n=7 as evidenced by the sudden appearance of a band at 1800 wn. DFT calculations are performed in support of this work and several possible interpretations of the experimental data will be presented.
Duncan Michael A.
Ricks Allen M.
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