Infrared Spectra of Acetylene-Nitrous Oxide Trimers: the (N_2O)_2-C_2H_2 and (N_2O)_2-C_2D_2

Details Infrared Spectra of Acetylene-Nitrous Oxide Trimers: the (N_2O)_2-C_2H_2 and (N_2O)_2-C_2D_2 Infrared Spectra of Acetylene-Nitrous Oxide Trimers: the (N_2O)_2-C_2H_2 and (N_2O)_2-C_2D_2

Jun 2009

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2009mss..confemg11d&link_type=abstract

"International Symposium On Molecular Spectroscopy, 64th Meeting, Held 22-26 June, 2009 at Ohio State University. http://molspec

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Infrared/Raman

Scientific paper

The spectra of the (N_2O)_2-C_2H_2 and ((N_2O)_2-C_2D_2 trimers in the region of the N_2O ν_1 fundamental ( 2224 cm-1) are observed using a tuneable diode laser to probe a pulsed supersonic slit jet expansion. The observed bands have c- and b-type rotational structure and the trimer has C_2 symmetry. The structure of the trimer can be thought of as a nonpolar N_2O dimer with a C_2H_2 monomer lying above the dimer plane. Search for the other possible isomers of the trimer is currently underway.

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