Infrared Photodissociation Spectroscopy of First Row Transition Metal-Carbonyl Cations

Details Infrared Photodissociation Spectroscopy of First Row Transition Metal-Carbonyl Cations Infrared Photodissociation Spectroscopy of First Row Transition Metal-Carbonyl Cations

Jun 2011

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..confemi04b&link_type=abstract

"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec

Computer Science

Radicals And Ions

Scientific paper

Transition metal-carbonyl cations are generated in a laser vaporization/supersonic expansion cluster source, mass selected and studied using infrared laser photodissociation spectroscopy. The carbonyl stretching region (2050-2350 Cm-1) is probed using a tunable infrared OPO/OPA system. Several cluster sizes are investigated and insight into their stability and geometry is obtained. Cu(CO)_4+ has a complete coordination sphere, consistent with 18-electron stability and a tetrahedral structure similar to that of isovalent Ni(CO)_4. Ti(CO)_6+ has a complete coordination sphere and does not satisfy the 18-electron rule. DFT calculations are performed and reported to corroborate the experimental data.

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