Infrared fundamental bands of O13C17O isotopic variants of carbon dioxide.

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Carbon Dioxide: Laboratory Spectra, Carbon Dioxide: Infrared Spectra

Scientific paper

Infrared spectra of a carbon dioxide sample enriched with oxygen-17 have been recorded with a resolution of about 0.0025 cm-1 in the regions of the fundamental bands ν3 (600-800 cm-1) and ν3 (2200-2400 cm-1), using the long path difference Fourier transform spectrometer of the LPMA in Paris. The ν3 fundamental bands of 17O13C17O and 17O13C18O have been studied for the first time. For each species a simultaneous reduction of all spectroscopic data has been carried out, yielding new or improved spectroscopic constants. Line intensities of the ν3 band of 16O13C17O have been also reported, and isotopic rules for the rotationless transition dipole moment of carbon dioxide have been used to derive calculated values from isotopic substitution for ν3 bands which are compared with experimental ones.

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