In situ structural investigation of iron-containing silicate liquids and glasses

Details In situ structural investigation of iron-containing silicate liquids and glasses In situ structural investigation of iron-containing silicate liquids and glasses

Apr 1995

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1995gecoa..59.1571w&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 59, Issue 8, pp.1571-1577

Computer Science

4

Scientific paper

In situ high-temperature Raman spectra are presented below and above the glass transition temperature ( T g ) of the 0.5Na 2 O·0.5Fe 2 O 3 ·3SiO 2 (Fe-albite, NFS0), 1.5Na 2 O·0.5Fe 2 O 3 ·3SiO 2 (NFS2), K 2 O·0.5Fe 2 O 3 ·3SiO 2 (KFS), and reduced K 2 O·FeO·3SiO 2 (KFS-R) compositions. For the oxidized sample, there is a close structural relationship between the glass and the super-cooled melt above T g . With increasing temperature, no coordination changes of Fe 3+ and no new anionic species are observed in the oxidized melts. In the spectrum of fully polymerized Fe-albite (Fe-Ab) glass, the increase in linewidth of the low frequency Raman band at 452 cm -1 and shift in the position of the band to higher frequency at high temperature indicate an increase in the extent of disorder and decrease of average T-O-T angle, where T = Si, Fe 3+ in tetrahedral coordination. In the depolymerized glasses, (NFS1) and KFS, the increase in intensities of the Raman bands associated with Q 3 species, containing three bridging oxygen atoms per T cation, result from either a change in relative cross sections of Raman modes or from a net increase in Q 3 species with increasing temperature. On the basis of observed changes in the Raman spectra of the reduced sample (KFS-R), it is proposed that most of the Fe 2+ ions act as network modifier. This suggestion is justified by the observation of the polarization character of the spectra and the appearance of new Raman bands.

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