Identification of Jupiter's 10-μ m Ammonia Ice Feature in CIRS Data

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We present the first detection of NH3 ice in the thermal infrared in Jupiter's atmosphere using Cassini CIRS observations in the 10-μ m region obtained on 31 December 2000 and 1 January 2001.
We quantify the strength of the NH3 ice feature by calculating a brightness temperature difference α defined by subtracting the brightness temperature at 1060 cm-1 from the brightness temperature of an adjacent continuum region at 1040 cm-1. Using midlatitude zonally averaged CIRS spectra, we demonstrate systematic spatial variations in α , with the highest values (implying a stronger NH3 ice signature) at the equator and near 23o N.
In one CIRS spectral average (covering 22o to 25o N and 140o to 240o W), our models indicate an optical depth of 0.75+/-0.25 for NH3 ice particles modeled as randomly oriented 4:1 prolate spheroids (volume equivalent radius = 0.79 μ m). We choose prolate spheroid particles based on laboratory studies of NH3 ice aerosols, although 1-μ m Mie-scattering spheres would also have detectable signatures at 1060 cm-1. Particles larger or smaller than 1 μ m by a factor of 2 or more would be unable to duplicate the observed NH3 ice feature at 1060 cm-1: absoprtion due to larger particles is excessively broadened, and absorption due to smaller particles is hidden by NH3 gas absorption at 1067 cm-1. In a spectrum of a second region on Jupiter (14o to 17o N and 10o to 70o W), we find an upper limit of τ = 0.2 for the same NH3 ice particle type.
In our models, the 1060 cm-1 feature appears only when NH3 ice is present at P <= 500 mbar, suggesting that the detected particles are distinct from the deeper higher-opacity grey cloud required to match data from both CIRS and other previous infrared studies.

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